PC only (Mac later)
PHYSICAL CHEMISTRY eBOOK Kinetics module
By LAIDLER, MEISER AND SANCTUARY
Chapter 1 comes with all the modules. The Chemical Kinetics Module was written by Professor K. Laidler, a leading kineticist, and covers chapters 9 and 10 of the Physical Chemistry eBook. You can see the detailed Table of Contents by clicking the "Contents" tab just above this text. Only available in dowload format, the Chemical Kinetics chapters cover all the basic ideas along with extensive applications and examples.
The multimedia opens on the relevant pages and allows the student to visualize many of the concepts by varying parameters and plotting different graphs. For example by varying initial conditions and rate constants, the student can follow the kinetics of different types of reactions: opposing, consecutive, parallel and chain reactions. They can easily see how the steady-state approximation works as well as other common conditions, such as the bottle neck effect and the rate determining step.
The chapters deal first with the definitions of rates and then move into explaining rate laws and half lives. After this, the emphasis moves into mechanisms, so important in modern chemistry, and which are applicable to processes from organic reactions to nanotechnology. The important theories of the rate constant, such as hard sphere collisions and Transition State Theory complete this comphensive treatment of Kinetics. In addition, to the the clearly written material, vivid figures and many worked examples, the user can listen to explanations and interact with the multimedia. All these allow the student to learn Physical Chemistry efficiently and meets the modern needs of those who have grown up with computers.
Download the
Chemical Kinetics Solutions Manual for free. It contains the solutions to all the problems as worked out by students themselves. This peer learning model is a valuable asset for students. Check for up-dates.
Chapter 9
Chemical Kinetics I. The Basic Ideas
9.1 Rates of Consumption and Formation
9.2 Rate of Reaction
9.3 Empirical Rate Equations
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Order of Reaction Reactions; Having No Order Rate Constants; and Rate Coefficients.
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9.4 Analysis of Kinetic Results
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Method of Integration; Half-Life Differential Method; Reactions Having No Simple Order; Opposing Reactions. |
9.5 Techniques for Very Fast Reactions
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Flow Methods; Pulse Methods.
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9.6 Molecular Kinetics
9.7 The Arrhenius Equation
9.8 Potential-Energy Surfaces
9.9 The Preexponential Factor
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Hard-Sphere Collision Theory; Transition-State Theory.
Biography: Henry Eyring
Quantum-Mechanical Tunneling; Kinetic-Isotope Effects.
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9.10 Reactions in Solution
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Influence of Solvent; Dielectric Constant; Influence of Ionic Strength;
Influence of Hydrostatic Pressure; Diffusion-Controlled Reactions;
Linear Gibbs Energy Relationships.
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9.11 Reaction Dynamics
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Molecular Beams; Chemiluminescence; Dynamical Calculations; The Detection of Transition Species.
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Key Equations
Problems
Suggested Reading
Chapter 10
Chemical Kinetics II. Composite Mechanisms
10.1 Evidence for a Composite Mechanism
10.2 Types of Composite Reactions
10.3 Rate Equations for Composite Mechanisms
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Consecutive Reactions; Steady-State Treatment; Rate-Controlling (Rate-Determining) Steps.
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10.4 Rate Constants, Rate Coefficients, and Equilibrium Constants
10.5 Free-Radical Reactions
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Chain Reactions; Organic Decompositions.
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10.6 Photochemical Reactions
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The Photochemical Hydrogen-Chlorine Reaction; The Photochemical Hydrogen-Bromine Reaction; Photosensitization Flash Photolysis.
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10.7 Radiation-Chemical Reactions
10.8 Explosions
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The Initiation of an Explosion; The Transmission of an Explosion;
Detonations Explosion; Limits in Gaseous Explosions; Cool Flames.
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10.9 Catalysis
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Acid-Base Catalysis; Brønsted Relationships Enzyme Catalysis.
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10.10 Reactions in Solution: Some Special Features
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Collisions and Encounters.
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10.11 Mechanisms of Polymerization in Macromolecules
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Introduction Addition Polymers; Step-Growth Polymerization; Ionic
Polymerizations; “Living” Polymers; Heterogeneous Polymerization
Emulsion; Polymerization.
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10.12 Kinetics of Polymerization
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Free-Radical Polymerization; Condensation Polymerization.
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10.13 Induction Periods, Oscillations, and Chaos
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Clock Reactions; Oscillating Reactions; Cool Flames; The Belousov-Zhabotinsky Reaction; Chaos in Chemical Reactions. |
10.14 Electrochemical Dynamics
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Kinetics of Electrode Reactions; Polarography Electrokinetic Effects:
The Electric Double Layer; Electroosmosis ;Electrophoresis ;Reverse
Isoelectric Effects.
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Key Equations
Problems
Suggested Reading
Target audience
Covers all the traditional and modern topics in Physical Chemistry in undergraduate physical science programs.
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Volume Discounts (found at the bottom of all product pages). These provide even greater savings over our already low prices, compared to hard copy textbooks.
Users: teachers
With the programs loaded on the teachers laptop, the material can be projected in class. In addition throughout the text are scattered about 100 multimedia interactions that pop-up. In class, using the Multimedia Table of Contents , these interactions can be used as demonstrations.
Easy navigation with all sections and subsections linked to the Table of Contents..
Integrated into The Web with ready links to websites like Wikipedia, Google search, More Chemistry Help, etc.
In the flash version, an oular tool allows for important sections of the text to be highlighted and magnified, with the rest of the text dimmed. This is useful for students to keep their place while reading and for teachers to emphasize a point in class.
The multimedia pop-ups give students a chance to visualize and interact with programs that demonstrate different concepts.
The text provides detailed treatment of concepts that students often find challenging. Most of these are illustrated by worked examples.
eBooks are
green and today students have grown up reading and interacting with computers. Students are not only comfortable with electronic media, but for ecological reasons alone, eBook must replace hard copy.
Users: Students
This eTextbook provides many more features than are possible with hard textbooks, and does this at a much reduced price. Although all the undergraduate topics in physical chemistry are covered, you may not need to take them all. For this reason, the textbook is broken into smaller modules that cover specific topics. This provides an even greater saving.
Easy navigation, convenient hyperlinking and many features that enhance your ability to find material easily so you can concentrate on learning.
Fully integrated into The Web, with links to Wikipedia, Google, More Chemistry Help, and other useful on-line resources.
Interesting and informative multimedia components are built into the book and pop-up when clicked so you can listen to explanations of the material you are working on, and perform interactions that will help you understand the concepts.
In the flash version, a reading ocular allows you to magnify and focus on specific areas of text material. This helps you to keep your place while reading. In addition there is an underline tool that permits you to highlight text.
Note-taking tool allows you to jot down your thoughts as you go, or to keep reminders. (Flash version only)
Extensive problems are provided that are an essential part of studying for Physical Chemistry. A full solution manual is available for free. This solution manual was written by students for students. It is well known that peer learning is effective, and therefore the worked-out problems provide a valuable tool for all those interested in understanding physical chemistry at the required level.
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