Here is a list of the Physical Chemistry topics that are part of the IITJEE syllabus and their corresponding chapters in the latest, interactive edition of Physical Chemistry – Laidler, Meiser, Sanctuary.
Gaseous and liquid states
Chapter 1
- Absolute scale of temperature, ideal gas equation
- Deviation from ideality, van der Waals equation
- Kinetic theory of gases, average, root mean square and most probable velocities and their relation with temperature
- Law of partial pressures
- Vapour pressure
- Diffusion of gases
Energetics
Chapters 2 and 3
- First law of thermodynamics
- Internal energy, work and heat, pressure-volume work
- Enthalpy, Hess’s law
- Heat of reaction, fusion and vapourization
- Second law of thermodynamics
- Entropy
- Free energy
- Criterion of spontaneity.
Chemical equilibrium
Chapter 4
- Law of mass action
- Equilibrium constant, Le Chatelier’s principle (effect of concentration, temperature and pressure)
- Significance of DG and DGo in chemical equilibrium
- Solubility product, common ion effect, pH and buffer solutions
- Hydrolysis of salts.
Electrochemistry
Chapters 7 and 8
- Electrochemical cells and cell reactions
- Electrode potentials
- Nernst equation and its relation to DG
- Electrochemical series, emf of galvanic cells
- Faraday’s laws of electrolysisElectrolytic conductance, specific, equivalent and molar conductance, Kohlrausch’s law
- Concentration cells.
Chemical kinetics
Chapters 9 and 10
- Rates of chemical reactions
- Order of reactions
- Rate constant
- First order reactions
- Temperature dependence of rate constant (Arrhenius equation).
Solid state
Chapter 16
- Classification of solids, crystalline state, seven crystal systems (cell parameters a, b, c, a, b, g), close packed structure of solids (cubic), packing in fcc, bcc and hcp lattices
- Nearest neighbours, ionic radii, simple ionic compounds, point defects.
Solutions
Chapter 5
- Raoult’s law
- Molecular weight determination from lowering of vapor pressure, elevation of boiling point and depression of freezing point.
Surface chemistry
Chapter 18
- Elementary concepts of adsorption (excluding adsorption isotherms)
- Colloids
- Types, methods of preparation and general properties
- Elementary ideas of emulsions, surfactants and micelles (only definitions and examples).
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Written by: MCH Multimedia
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